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101.
Adsorption performance of activated carbon adsorbers in the downstream duct of vehicle spray painting booths has been studied to understand whether fine paint particles in the off-gas would deteriorate the adsorption capacity of volatile organic compounds (VOCs) on activated carbons. Three forms of activated carbons were selected and their properties were determined using nitrogen adsorption analysis, the measurement of pH value and total ash content, energy dispersion spectrometer, field-emission scanning electron microscopy, and thermogravimetric analysis. Results show that the adsorption capacity of activated carbon strongly depends upon its available specific surface area. When the total uptake on activated carbon approaches saturation, the vapors adsorbed would commence to get displaced by the paint particles gradually as time elapses and finally the uptake of vapors and paint particles reach equilibrium. Microporous carbons, in particular, were much more susceptible to paint particles. A Langmuir-type model for the uptake on activated carbons was suggested, which successfully described the adsorption behaviors of the off-gas released from vehicle spray painting booth. 相似文献
102.
Both cooperation and conflict between the sexes are commonplace in monogamous mating systems. However, little is known about
how cooperation and competition varies seasonally in monogamous species that maintain permanent territories. We presented
territorial pairs of male and female New Zealand robins (Petroica australis) with a large supply of insect prey at monthly intervals for 2 years. Behavioural observations after food presentation were
then made to quantify seasonal and sexual differences in aggressive interactions over prey, prey acquisition rates, mate provisioning,
offspring provisioning, selfish food hoarding and cache retrieval. Data were used to evaluate sex-specific behavioural strategies
of mediating competition for food. Results showed that males aggressively excluded females from experimental food sources
year-round. Females only accessed food sources when males left them unattended. Consequently, females acquired fewer prey
than males. After controlling for differences in prey acquisition, both sexes consumed similar amounts of prey in the non-breeding
season. Even though males aggressively excluded females from accessing food sources directly, males fed large amounts of prey
to females during the breeding season. Both sexes provisioned young at similar rates. Males cached less prey than females
in the breeding season but more prey than females in the non-breeding season. Females showed similar caching intensities year-round.
Although males tried to defend their hoards, females frequently retrieved male-made caches. Overall, results showed that although
New Zealand robins cooperate to raise offspring during the breeding season, conflict between the sexes occurs year-round.
Males and females display different behavioural strategies to gain access to experimental food sources, which appear to lessen
male–female competition for food and evenly distribute food resources between the sexes. 相似文献
103.
Shangtao Liang Randall "David" Pierce Jr. Hui Lin Sheau‐Yun Chiang Qingguo "Jack" Huang 《补救:环境净化治理成本、技术与工艺杂志》2018,28(2):127-134
The electrochemical oxidation (EO) of environmentally persistent perfluorooctanoic acid (PFOA) and perfluorooctanesulfonic acid (PFOS) with a Magnéli phase Ti4O7 electrode was investigated in this study. After 3 hours (hr) of electrolysis, 96.0 percent of PFOA (10 milligrams per liter [mg/L] in 100 milliliters [mL] 100 millimolar [mM] Na2SO4 solution) was removed following pseudo first‐order kinetics (k = 0.0226 per minute [min]) with the degradation half‐life of 30.7 min. Under the same treatment conditions, PFOS (10 mg/L in 100 mL 100 mM Na2SO4 solution) removal reached 98.9 percent with a pseudo first‐order degradation rate constant of 0.0491/min and the half‐life of 14.1 min. Although, the degradation of PFOA was slower than PFOS, when subjected to EO treatment in separate solutions, PFOA appeared to degrade faster than PFOS when both are present in the same solution, indicating possible competition between PFOA and PFOS during Ti4O7 anode‐based EO treatment with PFOA having the competitive advantage. Moreover, the EO treatment was applied to degrade highly concentrated PFOA (100.5 mg/L) and PFOS (68.6 mg/L) in ion‐exchange resin regenerant (still bottom) with high organic carbon content (15,800 mg/L). After 17‐hr electrolysis, the total removal of PFOA and PFOS was 77.2 and 96.5 percent, respectively, and the fluoride concentration increased from 0.84 mg/L to 836 mg/L. Also, the dark brown color of the original solution gradually faded during EO treatment. In another test using still bottom samples with lower total organic carbon (9,880 mg/L), the PFOA (15.5 mg/L) and PFOS (25.5 mg/L) concentrations were reduced to levels below the limits of quantification after 16‐hr treatment. In addition, the performance of EO treatment using different batch reactor setups was compared in this study, including one‐sided (one anode:one cathode) and two‐sided (one anode:two cathodes) setups. The two‐sided reactor configuration significantly enhanced the degradation efficiency, likely due to the larger anode area available for reactions. 相似文献
104.
Over decades of economic development, China's industrialization has led to significant environmental issues due to unregulated discharges into air, water, and soil. As cities continue to expand (i.e., urbanization trend) and awareness/concerns about environmental pollution rises, many industrial facilities along the edge of or within the city boundaries have been relocated or closed. This urbanization trend leaves behind idled and abandoned land that is contaminated from the former industrial activities and unregulated discharges. China released its first nationwide soil quality survey in April 2014, and the survey suggests that soil conditions in China represent a significant challenge. China has encouraged local engineering firms to demonstrate soil treatment technologies through pilot‐scale studies, but the outcomes of many demonstrations have not been promising due to the lack of remediation experience and underdeveloped technical guidelines that are needed to guide the remediation processes. During the past decade, some local soil remediation experience has been established, but it is limited for certain technologies that address their primary contaminants of concern: heavy metals and persistent organic pollutants. In 2014, national technical guidelines were published regarding environmental investigation, risk assessment, monitoring, and remediation; however, regulations and funding systems are still underdeveloped. Thus, the remediation processes that should maximize economic and environmental benefits are not streamlined. This article provides an overview of the latest regulatory developments, remediation technologies applied, technology trends, and market opportunities in China. The provided information aims to allow international remediation practitioners to better understand and appreciate this unique and emerging remediation market, which is growing fast, and to highlight the importance of developing a sustainable model that not only provides for cleanup of the environment but also supports economic development. ©2015 Wiley Periodicals, Inc. 相似文献
105.
Guor-Cheng Fang Chaur-Tsuen Lo Hung-Che Chiang Yu-Cheng Chen Yu-Chen Kuo Yuan-Jie Zhuang 《Environmental Forensics》2014,15(4):306-311
The main purpose of this study was to monitor ambient air particulates and particulate-bound Hg (Hg[p]) compositions in different crops in the coastal zone in the Taichung, Taiwan, area at a sampling site during 2013 October to 2013 December. In addition, a direct mercury analyzer (DMA-80) was used to directly detect the concentration with measured results by the regression equation of Hg in the ambient air. The results indicated that: 1) the mean values of ambient air Hg(p) compositions in rice displayed no significant differences for weeks one, two, and three versus those of the other crops (white cabbage, Arden lettuce, and Gynura procumbens); 2) for white cabbage, the higher the humidity, the lower the average ambient air Hg(p) compositions that were obtained, a phenomenon that was also reflected on the crops of white cabbage and G. procumbens; 3) Arden lettuce displayed no significant differences in the leaf Hg(p) compositions during weeks one, two, and three; however, the stem portions displayed significant differences in Hg(p) compositions during weeks two and three; and 4) the Spearman statistical method showed the mean differences for ambient air Hg(p) at the Long-jing sampling site (coastal regions) with four different crops (rice, white cabbage, Arden lettuce, and Gynura) in central Taiwan. The results further revealed no significant differences in mean values. 相似文献
106.
Chang-Tai?ChaoEmail author Arthur?L.?Dryver Tzu-Ching?Chiang 《Environmental and Ecological Statistics》2011,18(3):543-568
Rao-Blackwellization is used to improve the unbiased Hansen–Hurwitz and Horvitz–Thompson unbiased estimators in Adaptive Cluster
Sampling by finding the conditional expected value of the original unbiased estimators given the sufficient or minimal sufficient
statistic. In principle, the same idea can be used to find better ratio estimators, however, the calculation of taking all
the possible combinations into account can be extremely tedious in practice. The simplified analytical forms of such ratio
estimators are not currently available. For practical interest, several improved ratio estimators in Adaptive Cluster Sampling
are proposed in this article. The proposed ratio estimators are not the real Rao-Blackwellized versions of the original ones
but make use of the Rao-Blackwellized univariate estimators. How to calculate the proposed estimators is illustrated, and
their performance are evaluated by both of the Bivariate Poisson clustered process and a real data. The simulation result
indicates that the proposed improved ratio estimators are able to provide considerably advantageous estimation results over
the original ones. 相似文献
107.
Kai-Ying Chiang Tsan-Yao Chen Chih-Hao Lee Tsang-Lang Lin Ming-Kuang Wang Ling-Yun Jang Jyh-Fu Lee 《环境科学学报(英文版)》2013,25(3):626-636
This study investigates biogeochemical reductive release of arsenate from beudantite into solution in a crater area in northern Taiwan,using a combination of X-ray absorption near-edge structure (XANES) and atomic absorption spectrometry.Total arsenic (As) concentrations in the soil were more than 200 mg/kg.Over four months of laboratory experiments,less than 0.8% As was released into solution after reduction experiments.The 71% to 83% As was chemically reduced into arsenite (As(III)) and partially weathering into the soluble phase.The kinetic dissolution and re-precipitation of As,Fe,Pb and sulfate in this area of paddy soils merits further study. 相似文献
108.
Hung-Lung Chiang Cho-Ching Lo Sen-Yi Ma 《Environmental science and pollution research international》2010,17(3):624-633
Introduction
The pyrolytic method was employed to recycle metals and brominated compounds blended into printed circuit boards (PCBs). 相似文献109.
Bea V. Chang Bei W. Chiang Shaw Y. Yuan 《Journal of environmental science and health. Part. B》2013,48(4):387-392
This study investigated the effects of various factors on the anaerobic degradation of nonylphenol (NP) in soil. The results show that the optimal pH for NP degradation was 7.0 and that the degradation rate was enhanced when the temperature was increased. The addition of compost enhanced NP degradation. The individual addition of the electron donors lactate, acetate, and pyruvate inhibited NP degradation. The high-to-low order of NP degradation rates under three anaerobic conditions was sulfate-reducing conditions > methanogenic conditions > nitrate-reducing conditions. The results show that sulfate-reducing bacteria, methanogen, and eubacteria are involved in the anaerobic degradation of NP, with sulfate-reducing bacteria being a major component of the soil. Of the anaerobic strains isolated from the soil samples, strain AT3 expressed the best ability to biodegrade NP. 相似文献
110.
P.F.A.M. Römkens H.Y. Guo C.L. Chu T.S. Liu C.F. Chiang G.F. Koopmans 《Environmental pollution (Barking, Essex : 1987)》2009,157(8-9):2435-2444
Cadmium (Cd) levels in paddy fields across Taiwan have increased due to emission from industry. To ensure the production of rice that meets food quality standards, predictive models or suitable soil tests are needed to evaluate the quality of soils to be used for rice cropping. Levels of Cd in soil and rice grains were measured in 19 paddy fields across the western plains in Taiwan. Cadmium levels in soil range from less than 0.1 mg kg?1 to 30 mg kg?1. Measured Cd levels in brown rice were predicted very well (R2 > 0.8) based on Cd and Zinc in a 0.01 M CaCl2 extract or a soil–plant transfer model using the reactive soil Cd content, pH, and cation exchange capacity. In contrast to current soil quality standards used in Taiwan, such models are effective in identifying soils where Cd in rice will exceed food quality standards. 相似文献